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Cp1B and Cp2B are pseudodipeptide-forming ATP-grasp enzymes The putative ATP-grasp enzyme Cp1B and the ANL-family enzyme Cp1D are responsible for the amide bond-forming steps to give 1 and analogs

Si-Tayeb et al., 2010

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This quantitative understanding is now driving the development of pathway-specific inhibitors, such as PKC- selective antagonists, SGLT2 inhibitors, and glyoxalase-1, which have shown promise in preclinical models for breaking this cycle without globally suppressing physiologically important ROS signaling -Figure 3 (Oliveira et al., 2023